I have no knowledge of the process of wrangling, but I'm guessing it would start out as "Ladybug and Chat Noir RPF" and might stay that way for as long as all the other heroes are essentially guest star party members.

It might end up as the RPF of the most popular comic series about Ladybug and Chat Noir, on the idea that the Archive would be faster to tag and sort the fictional property than the real people, and would attach the real people in relation to their fictionalized selves.